Exploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis.

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dc.contributor.authorEng Poh, Ng
dc.date.accessioned2017-10-02T07:30:46Z
dc.date.available2017-10-02T07:30:46Z
dc.date.issued2017
dc.description.abstractThis project reported the synthesis of novel heterocyclic nitrogen-based ionic liquid molecules as novel structure-directing agents (SDAs) in the synthesis uf zeulite microporous materials. The first part of this project discussed about the synthesis of several types of heterocyclic nitrogen-based SDAs. The prepared SDAs were then characterized using IR, IH NMR, TG/DTG and CHN analyses. The experiment was then followed by the formation study of iron-containing AIPO-5 crystals in the presence of phosphorous acid (H3P03) by using imidazolium-based SDA ([bdmim ]el) under ionothermal condition. The formation process of FeAPO-5 during the ionothermal synthesis was monitored by microscopic and spectroscopic methods. The roles of Fe3+ and H3POJ in the formation of the FeAPO-5 framework were investigated. Possible mechanism for the growth of FeAPO-5 crystals was proposed based on the experimental results.en_US
dc.identifier.urihttp://hdl.handle.net/123456789/4772
dc.subjectheterocyclic nitrogenen_US
dc.subjectliquid moleculesen_US
dc.subjectstructureen_US
dc.subjectdirectingen_US
dc.titleExploratory study of heterocyclic nitrogen-based ionic liquids as supramolecular structure-directing agents in zeolite synthesis.en_US
dc.typeTechnical Reporten_US
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