Publication:
Preparation and characterization of inner self-healing rubber filled ground tyre rubber tape for puncture proof application

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Date
2024-06-01
Authors
Mimi Syahira, Masraff
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A self-healing natural rubber (NR) based on reversible metal-thiolate ionic networks was successfuy fabricated. Recycled tire rubber was added to the self- healing rubber compound with the aim of improving the healing properties of the rubber tape and promoting the sustainable development of rubber products. Different types of recycled tyre rubber (rubber shred (RS), rubber dust 30 mesh (RD30) and rubber dust 40 mesh (RD40)) were assessed in order to achieve optimal content of recycled tyre rubbers for efficient self-healing performance. The results revealed that self-healing rubber with 10 phr, RD40 showed 90% recovery from puncture damage for nail diameter below 3.4 mm. Subsequently, the effect of plasticizer was investigated to improve the dispersion of RD40 within the self-healing rubber matrix. The amount of plasticizer was varied at three different levels (3, 6 and 9 phr). It was found that addition of 9 phr plasticizer enable 100% recovery of puncture damage for nail diameter below 3.4 mm and 85-95% recovery for nail diameter of 4.0 mm. RD40 was also selectively modified by grafting with acrylic acid which contributed to additional formation of ionic cluster and enhanced rearrangement and reformation of reversible metal ioniic bonding between natural rubber and RD40 particles. The results showed 100% puncture recovery for smaller nail diameter and notorious increased in healing efficiency up to 90-97% for 4.0 mm nail diameter. This promising result open path for development of puncture-proof self-healing tyre.
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