Synthesis,characterization and reactivity of mixed-metal cluster carbonyls.

dc.contributor.author	Shawkataly, Omar
dc.date.accessioned	2017-10-03T02:58:09Z
dc.date.available	2017-10-03T02:58:09Z
dc.date.issued	2017
dc.description.abstract	Series of RU3(CO)g(arphos)(L) complexes where L = PCY3. PPh3. P(C6H4F-mh, P(C6H4F-ph. P(C6H4CIph and PPh(C6H40Me-ph. and complexes of the type LAuCI where L= AS(C 21H2rP). AS(C21H21-m), Ph2As(CH2hAsPh2 and As(C30H21 ) were synthesized and characterized by spectroscopic and analytical techniques. The molecular structures of complexes have been determined by single X-ray diffraction analysis. The geometry structural and reactivity of the complexes are discussed. The elongation of Ru-Ru bonds within the RU3(CO)g(arphos)(L) is controlled by steric interaction between the group 15 monodentate ligand and CO on the adjacent Ru atom. Besides, the electronic effects accounting for this phenomenon are discussed. The Ru-P bond lengths can be attributed to the different electronic and the size of the cone angle.	en_US
dc.identifier.uri	http://hdl.handle.net/123456789/4789
dc.subject	Synthesis	en_US
dc.subject	Characterization	en_US
dc.subject	Mixed-Metal	en_US
dc.subject	Cluster Carbonyls	en_US
dc.title	Synthesis,characterization and reactivity of mixed-metal cluster carbonyls.	en_US
dc.type	Technical Report	en_US

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